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Aquarium Nitrates; Lowering Nitrate Levels, How to Control

 

By Carl Strohmeyer
Updated 10/22/14

AQUARIUM OR POND NITRATES
Including:
OVERVIEW

Although much less toxic than ammonia and nitrite; Nitrate (NO3) as a nitrogen compound also causes stress at all levels making a fish’s organs work harder to adjust to their environment, especially at levels higher than 100 ppm.
The increasing stress results in the loss of ability to fight diseases, the ability to heal itself, and the ability to reproduce.
It is essential for you, the aquarium hobbyist, to maintain a proper environment for your aquatic companions. High nitrate levels are often a sign of poorly maintained aquariums and will cause problems in the long term.

As a generalization, I recommend levels UNDER 40-50 ppm for FW, 20 ppm for Saltwater fish, & under 5 ppm or less for reef aquariums. For planted freshwater aquariums, about 15 ppm is suggested (not much lower).
If levels exceed these generalized numbers for a long period, not just a day or even a week, coupled with other water parameter factors such as poor Redox balance, this can and will affect long term fish health.
Further Reference: Aquarium Redox

Aquarium Nitrate Control; Test KitNitrates are potentially dangerous due to the effects on the water chemistry and on a healthy environment for your fish while nitrates are accumulating.
The higher the nitrate levels, the higher and more severe the consequences due to the stress on your fish and the favorable conditions for a serious algae outbreak.

Nitrate levels around 5 ppm or less are found in nature which provides an almost nitrate free environment (although a Nitrate level of around 15 ppm is usually best for planted freshwater aquariums as noted earlier).
The higher the nitrate concentration the more stress for the fish. More severe stress is reached at levels exceeding 100 ppm. Many plants will fail before reaching this level.
Additional stress MAY be added due to an accumulation of life forms such as detritus worms feeding on decomposing waste, and the consequently higher biomass (organisms living in the aquarium) leads to an increasing demand of oxygen.
Reference: Aquarium Planaria? Actually Detritus Worms

I will also add that although nitrates are not dangerous in the short term unlike ammonia or nitrites; in established tanks I usually test this parameter more often as this is a good indicator of how well I am doing in my tank cleanings. Example; if enough water is being changed and with the correct frequency, as well as to whether additional nitrate removing products or procedures need to be employed. Tests of KH & GH are also useful in indicating an established tanks health.
Reference: Aquarium Cleaning; Reasons, Frequency, more

One more point about nitrate; I have tested the water on under sized aquariums/bowls containing otherwise healthy goldfish.
The nitrates would often exceed 200 ppm! These goldfish (although they appeared healthy), rarely lived more than 3-5 years as compared to the 12 + years of the goldfish I have kept for clients in pond and larger aquariums.
University studies in Cattle show nitrate levels in water over 221 ppm to be harmful or even fatal, so I sure would NOT want my fish kept at nitrate levels approaching this number.



*WHAT ARE NITRATES?

Nitrates (NO3) are compounds composed of a nitrogen and three oxygen atoms and are often the final stage in the nitrogen cycle of fresh and saltwater aquariums if there are not nitrate removing plants, algae, or nitrate reducing anaerobic bacteria present.
Nitrates are the conjugate base (chemical substance that releases a proton in the backward chemical reaction) of nitric acid (HNO3), consisting of one central nitrogen atom surrounded by three identical oxygen atoms.
The presence or production of large amounts nitrates can result in the presence of Nitric acid according to the Brønsted-Lowry theory of acids and bases which will in turn affect an aquariums pH and KH (which can result in dangerous pH swings).

For more about the nitrogen cycle, please reference:
*Aquarium Nitrogen Cycle

Aquarium Nitrates, Bio LoadA high Bio-Load that often produces large amounts of organic mulm and decomposition in an aquarium (or pond) gravel or in filters is often a common cause of persistent nitrate problems.
Another clue to this is a pH that tends to drop quickly, often even with buffers added (assuming a higher new water pH); the breakdown of organic mulm or similar will lower pH while increasing nitrates.
Pockets of decomposing organics are often found in areas of deep fine sand, under rocks or other décor, or in large filters (especially canister filters).




*HIGH NITRATE DANGERS:

High nitrate levels which many sources based in human studies place as low as 30- 45 ppm of nitrate as harmful. The EPA recommend levels under 10 ppm in drinking water, although often this can higher especially in well water.
High nitrate levels can cause respiration problems in fish, lower or eliminate the ability to breed, resist disease, and lower activity of aquarium inhabitants.
In human studies high nitrate levels have been shown to dangerously lower blood pressure by causing the muscles that control the size of blood vessels to relax, this can be dangerous to fish too causing circulatory problems which can again result in poor disease resistance.
High Nitrate levels in aquariums will also result in high algae growths and in marine aquariums is toxic at even low levels to Cephalopods such as Octopus and to corals.

Another danger is in the bloodstream, nitrates can be converted biologically to nitrites, leading to "Brown Blood Disease".

For more on the dangers of Nitrates:
*Nitrates In Drinking Water

Temporary Relief of Nitrate Poisoning:
First, please note that high nitrates are not even close to the danger of high ammonia or nitrites for fish, so if these are the problem, high ammonia and nitrites should be addressed first.
Some have stated that moving from high nitrates to low nitrates or vice versa can also cause nitrate shock similar to pH shock, however this is anecdotal and my tests as well as research have yet to verify such claims (for one nitrates are NOT algorithmic like pH is).


Methylene Blue for Aquarium, aid fish nitrate poisoning*Medicated Baths using Methylene Blue can increase oxygen in the blood and quickly remedy ammonia, nitrite, and especially nitrate poisoning (in this order of effectiveness too with ammonia poisoning the least effective and nitrates the most effective).
See Reference: Performing Medicated Fish Baths, Dips, similar


Spirulina Algae aid for aquarium fish nitrate poisoning*Spirulina Algae or Chlorophyll Remedy; these build the immune system and increase blood oxygen levels in fish that have suffered from nitrite or nitrate poisoning or oxygen deprivation. Spirulina is the better choice of the two, being much better at increasing immune function.

The most simple and effective way to administer Spirulina is via a high Spirulina based food such as Spirulina 20 or HBH Veggie/Spirulina Flake. Feeding Spirulina based foods although not a replacement for lowering your aquarium or ponds nitrate levels can be a reasonable albeit partial solution to chronic nitrate problems for many fish (not reef inhabitants such as Corals, Cephalopods, etc.).

If you have access to food grade Spirulina or Chlorophyll, these can also be used as a bath: Pre-mix 1 ounce of spirulina or chlorophyll per gallon of aquarium water (I suggest first liquifying the powder with sterile water to a make a liquid ounce); allow fish to soak for 15-30 minutes; perform this once or twice a daily. Use a fresh bath for each bath using your display tank water. This can be performed in 1/2 ounces with 1/2 gallon too for smaller fish.

Please read this article for more about Spirulina Algae:
Spirulina Algae

Where to Purchase, Product References:
*Spirulina 20 Fish Food Flake
*HBH Veggie/Spirulina Flake

*Most importantly, follow the steps below to lower your aquarium or pond nitrates in the first place and often any possible nitrate poisoning issues will go away too.

*REMOVAL / PREVENTION:

Here are a few basics for removal/ prevention of nitrates (I will add to this list over time too)


Further Resources:

Please reference this other Aquarium answers article for more other filter media types as well:
Aquarium Filter Media; Types, Capacities and more

Please reference this article for more about the production of Hydrogen Sulfides during the process of De-Nitrification: Hydrogen Sulfide production in anaerobic De-Nitrification for Aquarium/Pond Nitrate Removal

For a map of Nitrates in World Rivers, please click below
Nitrate Levels in Major World Rivers

For more referenced aquarium information pertaining to:
*Freshwater Aquarium Care, Basics to Advanced
*Saltwater Aquarium Care, Basics to Advanced

Other Recommended Reference & Product Sites

The article below is a MUST READ for anyone interested in moving from basic aquarium keeping to more advanced aquarium keeping, including better Redox Balance:
Aquarium or Pond UV Sterilization
Ultraviolet Sterilization, Advanced Aquarium Keeping


Pond Care Information
POND CARE INFORMATION; Complete Steps


*UV Replacement Bulbs, LampsUV Replacement Lamps/Bulbs; Aquarium or Pond
For TRUE High Output, Hot Cathode, Low Pressure UVC Germicidal Bulbs, for aquarium or pond


AcroPower Amino Acids for Aquarium Reef Coral

AcroPower Amino Acids for SPS Corals

AcroPower supplies essential amino acids that corals need to build their skeletal architecture



*Sponge Filtration; Complete Information about the use of Sponge Filters in Aquarium or Pond



FISH AS PETS
Fish as Pets with articles & commentary of Interest to the Aquarium Hobby


Aquarium Power Head PumpSunSun JP-023 Aquarium Power Head Water Pumps

Superior performance and value when compared to many more well known brands such as Hagen or Marineland



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AQUARIUM ANSWERS;
ARTICLES:

In Chronological order of writing with the newest at the top
  1. Aquarium or Pond Bio Load
  2. Tuberculosis in Fish
  3. PUR vs PAR in Aquarium Lighting
  4. Head Pressure in Aquarium and Pond Water Pumps
  5. Betta Fin Rot
  6. Angelfish Virus/Aids
  7. Activated Carbon
  8. Fish Baths/Dips as an aid to treatment
  9. Streptococcus gram positive bacterium in aquariums, Eye Infections
  10. Hydrogen Sulfide
    production in anaerobic De-Nitrification for Aquarium/Ponds
  11. Fish Shipping
  12. Aquarium Size, Fish Stunting
  13. Aquarium Algae,
    BBA & Brown Algae in particular
  14. Aquarium Salt (Sodium chloride) in Freshwater Aquariums
  15. Betta Habitat; Wild Bettas to Domestic Betta environment parameters
  16. HITH; Hole in the Head Disease
  17. Aquarium Protein Skimmers, Ozonizers
  18. Power Head/ Water Pump Review
  19. Molly Disease/ Mollies in an Aquarium
  20. Basic Fish Anatomy, Fin Identification
  21. Aquarium Moving/ Power Failures
  22. Octopus as Aquarium Pets
  23. Aquarium Nitrates
  24. Ichthyophonus protists, fungus in fish
  25. Aquarium and Pond Filter Media
    Types; Mechanical, Bio, Chemical
  26. Aquarium Water Conditioners (also Pond)
  27. Fish Parasites; Trematodes & Monogeneans; Annelids and Nematodes;
    Flukes, internal worms, Detritus Worms (often confused with Planaria), Micro Worms
  28. Aquarium Silicone Application;
    DIY Aquarium Repair & Glass thickness
  29. Pond Veggie Filters; DIY Bog Filter
  30. The difference between Plaster of Paris and Aquarium Products such a Wonder Shells:
  31. NEON TETRA DISEASE
    Identification, prevention & Treatment
  32. AQUARIUM TEST KITS; Use & Importance
  33. SEXING FISH; Basics
  34. Chocolate Chip, Knobby and Fromia Starfish
  35. Freshwater Velvet & Costia
  36. Usnic Acid as a Fish Remedy
  37. Aquarium Heaters; Types, information
  38. The Lateral Line in Fish, Lateral Line Disease
    or Head and Lateral Line Erosion (HLLE)
  39. Tap Water use in Aquarium; Chloramines, Chlorine
  40. Can Black Ghost Knife fish give an electric shock?
  41. Bio Wheel Review; Do Bio-Wheels really work?
  42. How do Fish Drink?
    PROPER OSMOTIC FUNCTION-
    Use of RO Water
  43. Cyclops, and Predatory Damselfly larvae
  44. Betta with Dropsy;
    Treatment and Prevention of DROPSY in all fish
  45. pH and KH problems in African Cichlid Aquarium
  46. Aquarium Gravel, which size?
  47. Blue green algae, Cyanobacteria in Ponds/Aquariums
  48. AQUARIUM ANSWERS DIRECTORY



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